1 a thermoplastic polyamide; a family of high-strength resilient synthetic materials
2 a synthetic fabric
EtymologyArbitrary letters + -on (by analogy with cotton); the frequently heard claim that the word derives from abbreviations of New York ("NY") and London ("Lon") is a myth.
- (UK): /ˈnaɪlɒn/, /"naIlQn/
- (US): nīʹlän, /ˈnaɪlɑːn/, /"naIlA:n/
- Rhymes: -aɪlɒn
- Originally, the DuPont company trade name for polyamide, a copolymer whose molecules consist of alternating diamine and dicarboxylic acid monomers bonded together; now generically used for this type of polymer.
- A stocking
originally fabricated from nylon; also used generically for any
long, sheer stocking worn on a woman's legs.
- They left the strip club when they discovered the ladies only stripped down to their nylons.
- Bulgarian: найлон
- Croatian: najlon
- French: nylon
- German: Nylon
- Icelandic: nælon
- Persian: نایلون
- Swedish: nylon
Nylon is a generic designation for a family of synthetic polymers known generically as polyamides and first produced on February 28, 1935 by Wallace Carothers at DuPont. Nylon is one of the most common polymers and is technically a synthetic linen.
OverviewNylon is a thermoplastic silky material, first used commercially in a nylon-bristled toothbrush (1938), followed more famously by women's “nylons” stockings (1940). It is made of repeating units linked by peptide bonds (another name for amide bonds) and is frequently referred to as polyamide (PA). Nylon was the first commercially successful polymer and the first synthetic fiber to be made entirely from coal, water and air. These are formed into monomers of intermediate molecular weight, which are then reacted to form long polymer chains.
Nylon was intended to be a synthetic replacement for silk and substituted for it in many different products after silk became scarce during World War II. It replaced silk in military applications such as parachutes, flak vests, and was used in many types of vehicle tyres.
Nylon fibers are used in a great many applications, including fabrics, bridal veils, carpets, musical strings and rope.
Solid nylon is used for mechanical parts such as gears and other low- to medium-stress components previously cast in metal. Engineering grade nylon is processed by extrusion, casting, and injection molding. Type 6/6 Nylon 101 is the most common commercial grade of nylon, and Nylon 6 is the most common commercial grade of cast nylon. Nylon is available in glass-filled and molybdenum sulfide-filled variants which increase structural and impact strength and rigidity or lubricity.
Aramids are another type of polyamide with quite different chain structures which include aromatic groups in the main chain. Such polymers make excellent ballistic fibres.
ChemistryNylons are condensation copolymers formed by reacting equal parts of a diamine and a dicarboxylic acid, so that peptide bonds form at both ends of each monomer in a process analogous to polypeptide biopolymers. The numerical suffix specifies the numbers of carbons donated by the monomers; the diamine first and the diacid second. The most common variant is nylon 6-6 which refers to the fact that the diamine (hexamethylene diamine) and the diacid (adipic acid) each donate 6 carbons to the polymer chain. As with other regular copolymers like polyesters and polyurethanes, the "repeating unit" consists of one of each monomer, so that they alternate in the chain. Since each monomer in this copolymer has the same reactive group on both ends, the direction of the amide bond reverses between each monomer, unlike natural polyamide proteins which have overall directionality: C terminal → N terminal. In the laboratory, nylon 6,6 can also be made using adipoyl chloride instead of adipic It is difficult to get the proportions exactly correct, and deviations can lead to chain termination at molecular weights less than a desirable 10,000 daltons (u). To overcome this problem, a crystalline, solid "nylon salt" can be formed at room temperature, using an exact 1:1 ratio of the acid and the base to neutralize each other. Heated to 285 °C, the salt reacts to form nylon polymer. Above 20,000 daltons, it is impossible to spin the chains into yarn, so to combat this, some acetic acid is added to react with a free amine end group during polymer elongation to limit the molecular weight. In practice, and especially for 6,6, the monomers are often combined in a water solution. The water used to make the solution is evaporated under controlled conditions, and the increasing concentration of "salt" is polymerized to the final molecular weight.
DuPont patented nylon 6,6, so in order to compete, other companies (particularly the German BASF) developed the homopolymer nylon 6, or polycaprolactam — not a condensation polymer, but formed by a ring-opening polymerization (alternatively made by polymerizing aminocaproic acid). The peptide bond within the caprolactam is broken with the exposed active groups on each side being incorporated into two new bonds as the monomer becomes part of the polymer backbone. In this case, all amide bonds lie in the same direction, but the properties of nylon 6 are sometimes indistinguishable from those of nylon 6,6 — except for melt temperature (N6 is lower) and some fiber properties in products like carpets and textiles. There is also nylon 9.
Nylon 5,10, made from pentamethylene diamine and sebacic acid, was studied by Carothers even before nylon 6,6 and has superior properties, but is more expensive to make. In keeping with this naming convention, "nylon 6,12" (N-6,12) or "PA-6,12" is a copolymer of a 6C diamine and a 12C diacid. Similarly for N-5,10 N-6,11; N-10,12, etc. Other nylons include copolymerized dicarboxylic acid/diamine products that are not based upon the monomers listed above. For example, some aromatic nylons are polymerized with the addition of diacids like terephthalic acid (→ Kevlar) or isophthalic acid (→ Nomex), more commonly associated with polyesters. There are copolymers of N-6,6/N6; copolymers of N-6,6/N-6/N-12; and others. Because of the way polyamides are formed, nylon would seem to be limited to unbranched, straight chains. But "star" branched nylon can be produced by the condensation of dicarboxylic acids with polyamines having three or more amino groups.
The general reaction is:
- cross sections can be either
- trilobal to imitate silk
- multilobal to increase staple like appearance and hand
- Its most widely used structures are multifilament, monofilament, staple or tow and is available as partially drawn or as finished filaments.
- Regular nylon has a round cross section and is perfectly uniform. The filaments are generally completely transparent unless they have been delustered or solution dyed. Thus, they are microscopically recognized as glass rods.
- Molecular chains of nylon are long and straight variations but
have no side chains or linkages.
- Cold drawing (step 18 on the model) can align the chains so they are oriented with the lengthwise direction and are highly crystalline.
- Nylon is related chemically to the protein fibers silk and
- They both have similar dye sites but nylon has many fewer dye sites than wool.
Basic Concepts of nylon production
- The first approach: combining molecules with an acid (COOH) group on each end are reacted with two chemicals that contain amine(NH2)groups on each end.
This process creates nylon 6,6, made of hexamethylene diamine with six carbon atoms and acidipic acid, as well as six carbon atoms.
- The second approach: a compound has an acid at one end and an
amine at the other and is polymerized to form a chain with
repeating units of(-NH-[CH2]n-CO-)x.
- In other words, nylon 6 is made from a single six-carbon substance called caprolactam.
- In this equation, if n=5, then nylon 6 is the assigned name. (may also be referred to as polymer)
- Pleats and creases can be heat-set at higher temperatures
- Nylon is very easy to dye, but Nylon 6,6 is not
- Better dye Affinity
- Softer Hand
- Greater elasticity and elastic recovery
- Better weathering properties; better sunlight resistance
Full Nylon Production Model
Producers The producers of nylon include: Honeywell Nylon Inc., Invista, Wellman Inc. among many others. The Dupont Company, is the most famous pioneer of the nylon we know today. The companies above now produce the nylon used in our everyday lives.
- Variation of luster: nylon has the ability to be very lustrous, semilustrous or dull.
- Durability: its high tenacity fibers are used for seatbelts, tire cords, ballistic cloth and other uses.
- High elongation
- Excellent abrasion resistance
- Highly resilient (nylon fabrics are heat-set)
- Paved the way for easy-care garments
- High resistance to:
- insects, fungi and animals
- molds, mildew, rot
- many chemicals
- Used in carpets and nylon stockings
- Melts instead of burning
- Used in many military applications
Bulk propertiesAbove their melting temperatures, Tm, thermoplastics like nylon are amorphous solids or viscous fluids in which the chains approximate random coils. Below Tm, amorphous regions alternate with regions which are lamellar crystals.http://aml.arizona.edu/classes/mse222/1998/nylon66/mse222.htm The amorphous regions contribute elasticity and the crystalline regions contribute strength and rigidity. The planar amide (-CO-NH-) groups are very polar, so nylon forms multiple hydrogen bonds among adjacent strands. Because the nylon backbone is so regular and symmetrical, especially if all the amide bonds are in the trans configuration, nylons often have high crystallinity and make excellent fibers. The amount of crystallinity depends on the details of formation, as well as on the kind of nylon. Apparently it can never be quenched from a melt as a completely amorphous solid.
Nylon 6,6 can have multiple parallel strands aligned with their neighboring peptide bonds at coordinated separations of exactly 6 and 4 carbons for considerable lengths, so the carbonyl oxygens and amide hydrogens can line up to form interchain hydrogen bonds repeatedly, without interruption. Nylon 5,10 can have coordinated runs of 5 and 8 carbons. Thus parallel (but not antiparallel) strands can participate in extended, unbroken, multi-chain β-pleated sheets, a strong and tough supermolecular structure similar to that found in natural silk fibroin and the β-keratins in feathers. (Proteins have only an amino acid α-carbon separating sequential -CO-NH- groups.) Nylon 6 will form uninterrupted H-bonded sheets with mixed directionalities, but the β-sheet wrinkling is somewhat different. The three-dimensional disposition of each alkane hydrocarbon chain depends on rotations about the 109.47° tetrahedral bonds of singly-bonded carbon atoms.
When extruded into fibers through pores in an industrial spinneret, the individual polymer chains tend to align because of viscous flow. If subjected to cold drawing afterwards, the fibers align further, increasing their crystallinity, and the material acquires additional tensile strength.http://www.chemheritage.org/EducationalServices/nylon/chem/cold.html In practice, nylon fibers are most often drawn using heated rolls at high speeds.
Block nylon tends to be less crystalline, except near the surfaces due to shearing stresses during formation. Nylon is clear and colorless, or milky, but is easily dyed. Multistranded nylon cord and rope is slippery and tends to unravel. The ends can be melted and fused with a heat source such as a flame or electrode to prevent this.
When dry, polyamide is a good electrical insulator. However, polyamide is hygroscopic. The absorption of water will change some of the material's properties such as its electrical resistance. Nylon is less absorbent than wool or cotton.
Historical usesBill Pittendreigh, DuPont, and other individuals and corporations worked diligently during the first few months of World War II to find a way to replace Asian silk with nylon in parachutes. It was also used to make tires, tents, ropes, ponchos, and other military supplies. It was even used in the production of a high-grade paper for U.S. currency. At the outset of the war, cotton accounted for more than 80% of all fibers used and manufactured, and wool fibers accounted for the remaining 20%. By August 1945, manufactured fibers had taken a market share of 25% and cotton had dropped.
Some of the terpolymers based upon nylon are used every day in packaging. Nylon has been used for meat wrappings and sausage sheaths.
Use in compositesNylon can be used as the matrix material in composite materials, such as glass or carbon fiber, and yields a higher density than pure nylon.
EtymologyIn 1940 John W. Eckelberry of DuPont stated that the letters "nyl" were arbitrary and the "on" was copied from the suffixes of other fibers such as cotton and rayon. A later publication by DuPont (Context, vol. 7, no. 2, 1978) explained that the name was originally intended to be "No-Run" ("run" meaning "unravel"), but was modified to avoid making such an unjustified claim and to make the word sound better. The story goes that Carothers changed one letter at a time until DuPont's management was satisfied. But he was not involved in the nylon project during the last year of his life, and committed suicide before the name was coined.
Two theories about the origin of the name claim that it is an acronym of "Now you've lost, Old Nippon" (N.Y.L.O.N.), or that it stands for "New York-London". In the latter case, it is claimed that these were the two cities where the product was researched and developed, or that the inspiration came from a New York to London airplane ticket. There is no evidence for the 'airline ticket' theory, though some compelling evidence of the former from contemporary researchers at Oxford University who assisted in development...Oxford can be viewed as London from New York, but Nylox would have been more accurate.
- carpet fiber
- fishing lines
- nylon fiber
- toothbrush bristles
- airbag fiber
- auto parts: intake manifolds, gas (petrol) tanks
- slings and rope used in climbing gear and slacklining
- machine parts, such as gears and bearings
- metallized nylon balloons
- classical and flamenco guitar strings
- paintball marker bolts
- racquetball,badminton, squash, and tennis racquet strings
- Strings for String instruments
- Drumstick heads
- As filter media in sterlizing grade filters
- Flexible tubing
- Basketball netting
- Textiles by Sara J. Kadolph, ISBN 0131187694
External linksFor historical perspectives on nylon, see the Documents List of "The Stocking Story: You Be The Historian" at the Smithsonian website, by The Lemelson Center for the Study of Invention and Innovation, National Museum of American History, Smithsonian Institution.
nylon in Afrikaans: Nylon
nylon in Arabic: نايلون
nylon in Bulgarian: Найлон
nylon in Catalan: Niló
nylon in Czech: Nylon
nylon in Danish: Nylon
nylon in German: Polyamide#Nylon
nylon in Spanish: Nailon
nylon in Esperanto: Nilono
nylon in French: Nylon
nylon in Scottish Gaelic: Nàidhlean
nylon in Galician: Nailon
nylon in Korean: 나일론
nylon in Indonesian: Nilon
nylon in Italian: Nylon
nylon in Hebrew: ניילון
nylon in Lithuanian: Nailonas
nylon in Dutch: Nylon
nylon in Japanese: ナイロン
nylon in Norwegian: Nylon
nylon in Norwegian Nynorsk: Nylon
nylon in Polish: Nylon
nylon in Portuguese: Náilon
nylon in Russian: Нейлон
nylon in Simple English: Nylon
nylon in Slovenian: Najlon
nylon in Serbian: Најлон
nylon in Finnish: Nailon
nylon in Swedish: Nylon
nylon in Turkish: Naylon
nylon in Ukrainian: Нейлон
nylon in Chinese: 尼龙
Aralac, Avisco, Axminster, Celanese, Chemstrand, Dacron, Dynel, Georgette, Harris Tweed, Lastex, Leatherette, Manila, Orlon, Qiana, Revolite, Terylene, Ultrasuede, Velon, Vicara, acetate, acetate rayon, alpaca, angora, arras, astrakhan, baize, bast, batik, blanketing, broadcloth, broadloom, brocade, bunting, calico, cambric, canvas, carpeting, cashmere, castor, cheesecloth, chiffon, chinchilla, chintz, coating, coir, cord, corduroy, cotton, crash, crepe, crepe de chine, cretonne, crinoline, damask, denim, doeskin, drill, drilling, drugget, duck, duffel, felt, flannel, flannelette, flax, fleece, floss, foulard, frieze, fustian, gauze, gingham, gossamer, grenadine, grogram, grosgrain, gunny, haircloth, hemp, herringbone, hessian, homespun, hop sacking, horsehair, huck, huckaback, jersey, jute, kapok, lame, lawn, linen, linoleum, linsey-woolsey, lisle, list, llama hair, loden, longcloth, luster, mackinaw, mackintosh, madras, maline, manta, mantua, marquisette, mat, matting, melton, merino, messaline, mohair, moire, moleskin, mousseline de soie, murrey, muslin, nainsook, nankeen, near-silk, net, netting, oakum, oil silk, oilcloth, organdy, organza, paisley, panne, panne velvet, pepper-and-salt, percale, pique, plaid, plush, polyester, pongee, poplin, print, quilting, radium, raffia, rayon, rayon casheen, rep, rugging, russet, sackcloth, sacking, sailcloth, sarcenet, sateen, satin, say, seersucker, serge, shalloon, shantung, sharkskin, sheers, sheeting, shoddy, shot silk, silk, sisal, spandex, spun rayon, stamin, stammel, stockinette, stuff, suede, swansdown, tabaret, tabby, taffeta, taffety, tapestry, tarpaulin, tartan, terry cloth, tick, ticking, tricotine, tulle, tussah, tussore, tweed, twill, veiling, velours, velure, velvet, velveteen, voile, wash-and-wear fabric, watered fabric, webbing, wool, worsted, yarn, zephyr